Ligand influence in the selective gold-mediated synthesis of allenes.
نویسندگان
چکیده
The use of [(IPr)AuOH] permits the generation of gold(i)-amine complexes by a silver-free protocol. These in situ or well-defined complexes are used in a straightforward synthetic route to substituted allenes from propargylic acetates. The catalytic activity can be modulated as a function of the nature of the ligand bound to the gold-NHC moiety.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 48 شماره
صفحات -
تاریخ انتشار 2010